(Z)-N,N-Dimethyl-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide
نویسندگان
چکیده
The title compound, C(15)H(16)N(4)S, exists in the Z conformation with the thionyl S atom lying cis to the azomethine N atom. The shortening of the N-N distance [1.3697 (17) Å] is due to extensive delocalization with the pyridine ring. The hydrazine-carbothio-amide unit is almost planar, with a maximum deviation of 0.013 (2) Å for the amide N atom. The stability of this conformation is favoured by the formation of an intra-molecular N-H⋯N hydrogen bond. The packing of the mol-ecules involves no classical inter-molecular hydrogen-bonding inter-actions; however, a C-H⋯π inter-action occurs.
منابع مشابه
Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2 N,N′}neodymium(III)
In the title compound, [NdCl(3)(C(12)H(10)N(2)O)(3)], the central Nd(III) ion is nine-coordinated by six N atoms from three bidentate chelate N-[phen-yl(pyridin-2-yl)methyl-idene]hydroxyl-amine ligands and three Cl(-) ions, and displays a distorted tricapped trigonal prismatic geometry. The complex mol-ecules are stabilized by intra-molecular O-H⋯Cl hydrogen bonds.
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